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It is fairly unusual for bare steel (with paint) to peel, it rather will develop rust spots and blister off. The typical scenario is that your posts are galvanized and the galvanizing on the post is "rusting" which means its forming a zinc oxide layer (which is powdery) and pushing the paint off.
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The Best Way to Paint Bare Metal. Sometimes a rattle-can paint job is the best option. Once you've throughly cleaned the metal, try not to touch it since oil from your skin can get it dirty again.
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To me it also has a finish like a varnish, ie it has is a perceptible coating you can feel. However that may just be because I paint the stuff on fairly liberally!! For a lighter, but probably less heavy duty finish on mild steel, I can also recommend a light coating of Danish oil for anything that isnt going to be exposed to the elements.
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Before blast cleaning, visible deposits of oil or grease shall be removed by any of the methods specified in SSPC-SP 1 or other agreed upon methods. Steel - Water Blasting. Removal of oil grease dirt, loose rust, loose mill scale, and loose paint by water at pressures of 2,000 to 2,500 psi at a flow of 4 to 14 gallons per minute. Stucco
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